Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5402100 | Journal of Luminescence | 2011 | 8 Pages |
Abstract
⺠β-diketone is good Mg2+ binder in the ground state. ⺠Their excited state is more loosely bound compared to the ground state. ⺠Mg2+ form both ground and excited state isosbestic with all the four different diketones. ⺠Stabilisation of the diketone/Mg(II) complexes are the determining factor for this interaction. ⺠β-diketones themselves have ICT which is further enhanced due to the addition of Mg2+.
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Physical Sciences and Engineering
Chemistry
Physical and Theoretical Chemistry
Authors
Tandrima Chaudhuri, Manas Banerjee,