Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5402449 | Journal of Luminescence | 2010 | 6 Pages |
Abstract
In this paper, we explore a diimine ligand of 2-thiazol-4-yl-1H-benzoimidazole (TB) with strong electron donors in its molecule. In addition, an excess electron-donor moiety of carbazole is incorporated through an inert alkyl chain to form another diimine ligand of 1-(4-carbazolylbutyl)-2-thiazol-4-yl-1H-benzoimidazole (CTB). Their corresponding Cu(I) complexes are synthesized as well. Experimental data confirm that both the Cu(I) complexes are high-energy-emitting ones. What is more, it is found that the emitter's photoluminescent and thermal performances can be greatly improved when active hydrogen is eliminated. Using the CTB-based Cu(I) complex as a dopant, we realize green-emitting devices with a maximum brightness of 1500Â cd/m2 peaking at 525Â nm, and the device efficiency roll-off in these devices is largely depressed due to the shield provided by carbazole moiety.
Related Topics
Physical Sciences and Engineering
Chemistry
Physical and Theoretical Chemistry
Authors
Dansong Zhang,