Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5402778 | Journal of Luminescence | 2010 | 5 Pages |
Abstract
We present a new approach to modeling of homogeneous line shape in two-photon absorption (2PA) spectra of chromophores with large permanent dipole moment difference between the ground- and excited electronic states using numerical solution of stochastic two-level density matrix equation of motion. Good agreement with experimental 2PA line shapes is obtained for S1âS0 transition of Styryl 9 M, which allows us to estimate that the permanent dipole moment difference varies in this chromophore within the S1âS0 band in the range, Îμ=12-25 D.
Related Topics
Physical Sciences and Engineering
Chemistry
Physical and Theoretical Chemistry
Authors
Aleksander Rebane, Mikhail A. Drobizhev, Nikolay S. Makarov, Erich Beuerman, Christoph Nacke, Jüri Pahapill,