Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5403510 | Journal of Luminescence | 2008 | 4 Pages |
Abstract
In this work, we extended the investigation on the effect of co-dopant ions in Cr:LiNbO3 to tetravalent cation such as GeO2. A singularity in the relative intensity of the 4A2â4T1 and 4A2â4T2 absorption band was observed for a concentration of â¼1.5Â mol%, compared with 4.5Â mol% for Mg2+. The photoluminescence emission spectra also reveal a new emission band, at a lower energy than the [Cr]Li centre, corresponding to this threshold concentration. A charge compensation model is proposed to explain the role of cation impurities and results are compared with those of other valence impurities.
Keywords
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Physical Sciences and Engineering
Chemistry
Physical and Theoretical Chemistry
Authors
E. Camarillo, H. Murrieta, J.M. Hernandez, R. Zoilo, M.C. Flores, T.P.J. Han, F. Jaque,