Article ID Journal Published Year Pages File Type
5403510 Journal of Luminescence 2008 4 Pages PDF
Abstract
In this work, we extended the investigation on the effect of co-dopant ions in Cr:LiNbO3 to tetravalent cation such as GeO2. A singularity in the relative intensity of the 4A2→4T1 and 4A2→4T2 absorption band was observed for a concentration of ∼1.5 mol%, compared with 4.5 mol% for Mg2+. The photoluminescence emission spectra also reveal a new emission band, at a lower energy than the [Cr]Li centre, corresponding to this threshold concentration. A charge compensation model is proposed to explain the role of cation impurities and results are compared with those of other valence impurities.
Related Topics
Physical Sciences and Engineering Chemistry Physical and Theoretical Chemistry
Authors
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