Article ID Journal Published Year Pages File Type
5403643 Journal of Luminescence 2007 4 Pages PDF
Abstract
Stable photoluminescence (PL) from AgI nanoparticles embedded in silica glass was investigated at room temperature. The Z1,2 excitonic emission of AgI exhibits fine structure with spacing of ∼0.20 eV (1610 cm−1), which is assigned to the frequency of vibration in interfacial water species. The PL excitation spectrum displays two newly observed bands at 3.45 and 4.35 eV associated with AgI-silica interaction. We suggest that the excitons in AgI are localized in the AgI/SiO2 interface region before radiative recombination.
Related Topics
Physical Sciences and Engineering Chemistry Physical and Theoretical Chemistry
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