Article ID Journal Published Year Pages File Type
5403645 Journal of Luminescence 2007 4 Pages PDF
Abstract
The temperature dependence of the optical properties in poly [2-methoxy-5-(2′-ethylhexyloxy)-p-phenylene vinylene] (MEH-PPV) blending with 2-(4-biphenyl)-5-(4-tertbutylphenyl)-1,3,4-oxadiazole (PBD) has been investigated. The blending influence on the chain conformation and exciton energy migration in blend film is described. The PL emission from the pure and blend films are all blue shifted with increasing temperature. An addition of PBD in MEH-PPV films suppresses the relative intensity of 0-1 vibronic peaks at lower temperature. This phenomenon will not be promoted with increasing temperature, attributed to a temperature-dependent migration process of singlet excitons.
Related Topics
Physical Sciences and Engineering Chemistry Physical and Theoretical Chemistry
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