Article ID Journal Published Year Pages File Type
5405708 Journal of Magnetic Resonance 2013 8 Pages PDF
Abstract
► 13C solid state DNP experiments were conducted using trityl (OX63) radicals. ► A maximum DNP enhancement was reached around 20-40 K. ► DNP spectral line-shapes are temperature dependent. ► Both the solid effect (SE) and the cross effect (CE) mechanisms contribute. ► The SE contribution increases with decreasing temperature while the CE decreases.
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Related Topics
Physical Sciences and Engineering Chemistry Physical and Theoretical Chemistry
Preview
The interplay between the solid effect and the cross effect mechanisms in solid state 13C DNP at 95 GHz using trityl radicals
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