Article ID Journal Published Year Pages File Type
5405890 Journal of Magnetic Resonance 2012 7 Pages PDF
Abstract
► We compared spin relaxation in solution between Tempone and a nitronyl nitroxide. ► We measured T1 and T2 of the radicals by electron spin echo in the range 195-310 K. ► Our analysis exploits experimental T1 and T2 to separate the relaxation terms. ► For similar radical sizes the nitronyl nitroxide has consistently longer T1 and T2. ► The larger anisotropic dipolar interaction causes faster relaxation in nitroxides.
Related Topics
Physical Sciences and Engineering Chemistry Physical and Theoretical Chemistry
Authors
, , ,