Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5406296 | Journal of Magnetic Resonance | 2011 | 5 Pages |
Abstract
⺠An NMR method for polydispersity determination of linear polymers is presented. ⺠It is based on differential diffusion observed for main chain and extremity signals. ⺠A statistical analysis of the DOSY spectrum provides an accurate estimates of PDI. ⺠The Flory coefficient of the polymer chain has to be known. ⺠Results on PEO reveal a very good accuracy.
Related Topics
Physical Sciences and Engineering
Chemistry
Physical and Theoretical Chemistry
Authors
Justine Viéville, Matthieu Tanty, Marc-André Delsuc,