| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5407105 | Journal of Magnetic Resonance | 2009 | 4 Pages |
Abstract
A square-pyramidal mixed-halogen nickel(III) NCN-pincer complex (PipeNCN)NiClBr (where PipeNCNÂ =Â 2,6-bis(piperidinomethyl)phenyl) was structurally characterized. Bromine occupies apical position; pincer ligand and chlorine atom are in the basal plane. EPR detects that complex in solution exists as a mixture of two structural isomers with bromine or chlorine atoms in the top of pyramid.
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Authors
Konstantin A. Kozhanov, Michael P. Bubnov, Vladimir K. Cherkasov, Georgy K. Fukin, Nina N. Vavilina, Larisa Yu. Efremova, Gleb A. Abakumov,