Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5407506 | Journal of Magnetic Resonance | 2007 | 9 Pages |
Abstract
The merits of SPAM and FAM pulses for enhancing the conversion of triple- to single-quantum coherences in the two-dimensional MQMAS experiment are compared using 87Rb (spin IÂ =Â 3/2) and 27Al (IÂ =Â 5/2) NMR of crystalline and amorphous materials. Although SPAM pulses are more easily optimized, our experiments and simulations suggest that FAM pulses yield greater signal intensity in all cases. In conclusion, we argue that, as originally suggested, SPAM and FAM pulses are best implemented in phase-modulated whole-echo MQMAS experiments and that the use of SPAM pulses to record separate echo and antiecho data sets, which are then combined, generally yields lower signal-to-noise ratios.
Related Topics
Physical Sciences and Engineering
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Physical and Theoretical Chemistry
Authors
Thomas J. Ball, Stephen Wimperis,