Article ID Journal Published Year Pages File Type
5407705 Journal of Magnetic Resonance 2006 5 Pages PDF
Abstract
A sensitivity of recently developed method of amplitude-modulated continuous wave EPR (AM-CW-EPR) is studied depending on the parameters of the modulation field. The case of the significant saturation and high modulation frequency is addressed. It is found, that the rapid resonance passage effect is essential for AM-CW-EPR. However, its manifestation is different comparing to the conventional CW-EPR experiment. Both experimental data and numerical simulations support the enhancement of the AM-CW-EPR sensitivity under the rapid passage conditions for the modulating magnetic field, which is important for practical use of the method.
Related Topics
Physical Sciences and Engineering Chemistry Physical and Theoretical Chemistry
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