Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5407845 | Journal of Magnetic Resonance | 2006 | 9 Pages |
Abstract
Upon hydrogenation from para-hydrogen (p-H2), hyperpolarization transfer toward a heteronucleus may be possible even if the two protons are chemically equivalent in the final product (but not magnetically equivalent), provided that J couplings with the heteronucleus exist. It is however shown (theoretically and experimentally) that this transfer effectively occurs if the spin system in the hydrogenated molecule is of the type AAâ²X (A and Aâ² denoting the two protons originating from p-H2 and X the heteronucleus) but does not occur for a spin system of the A2A2â²X type. A theory has been worked out for assessing the details of the X spectrum (multiplet patterns) in the case of ALTADENA and PASADENA experiments. Experimental verifications are provided.
Related Topics
Physical Sciences and Engineering
Chemistry
Physical and Theoretical Chemistry
Authors
Silvio Aime, Roberto Gobetto, Francesca Reineri, Daniel Canet,