Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5408311 | Journal of Molecular Liquids | 2017 | 23 Pages |
Abstract
β-Estradiol residue in water is very dangerous and unacceptable due to its endocrine disturbing and carcinogenetic nature. Therefore, fast, effective and eco-friendly removal method of β-estradiol is described from water. The maximum removal of β-estradiol from water was 82% with 600 μg Lâ 1 amount of 17-β-estradiol, 60 min agitation time, 6.0 g Lâ 1 amount of functionalized iron nano particles, 11.5 pH and 25 °C temperature. Thermodynamic parameters confirmed the spontaneous and exothermic uptake of 17-β-estradiol. The uptake of 17-β-estradiol followed first order reaction and the mechanism of uptake was through liquid film diffusion. The supra-molecular mechanism of β-estradiol interaction with functionalized iron nano particles is described. The reported method is fast, effective and eco-friendly and can be applied for the uptake of β-estradiol from water at laboratory, pilot and industrial levels in any water system.
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Physical and Theoretical Chemistry
Authors
Imran Ali, Zeid A. Alothman, Abdulrahman Alwarthan,