Article ID Journal Published Year Pages File Type
5408415 Journal of Molecular Liquids 2017 19 Pages PDF
Abstract
The work is devoted to the discussion of the H-bond nature in rare enough water vapor. For achievement of this aim 1) the new inter-particle potential between water molecules is constructed and 2) the overlapping degree of electron shells for water molecules forming an isolated dimer is in details studied. In order to estimate the diameter of a molecule, the averaged inter-particle potential between water molecules is used. It is shown that the overlapping degree does not exceed 0.03 that leads to the conclusion about the electrostatic nature of H-bonds in water vapor.
Related Topics
Physical Sciences and Engineering Chemistry Physical and Theoretical Chemistry
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