Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5408983 | Journal of Molecular Liquids | 2017 | 5 Pages |
Abstract
The hydrogen-bonding interactions in protic and aprotic amide solvent mixtures, i.e., formamide (FA) and N,N-dimethylformamide (DMF), were investigated via low-frequency Raman spectroscopy, small-angle neutron scattering (SANS) experiments, and molecular dynamics (MD) simulations. In a neat amide system, the low-frequency Raman spectra R(ν)s were well reproduced by the corresponding S(ν) spectra derived from the MD simulations. The observed peaks in R(ν)s at around < 200 cmâ 1 were assigned to the intermolecular interactions, particularly in terms of the hydrogen-bonding network formation and its dimensionality in the liquid state. The SANS experiments for the FA-DMF mixtures demonstrated that the FA molecules forming an extended three-dimensional hydrogen-bonding structure in the neat system interacted with DMF molecules through the hydrogen bonds in the mixtures over the whole range of solvent compositions, resulting in a homogeneous mixing state. Additionally, the R(ν) spectra for the mixtures were represented by the corresponding S(ν) spectra. From the R(ν) and S(ν) spectra of the FA-DMF mixtures, we found that (1) the Raman band at around 110 cmâ 1 mainly originates from the libration mode of amide molecules in the chain-like hydrogen-bonded structure and (2) the higher frequency band (approximately 200 cmâ 1) was attributed to the libration of the FA molecule restricted by the three-dimensional hydrogen-bonded network, which remained even in the DMF-rich compositions.
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Related Topics
Physical Sciences and Engineering
Chemistry
Physical and Theoretical Chemistry
Authors
Kenta Fujii, Mari Yoshitake, Hikari Watanabe, Toshiyuki Takamuku, Yasuhiro Umebayashi,