Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5410236 | Journal of Molecular Liquids | 2016 | 7 Pages |
Abstract
A sensitive phenazopyridine sensor has been developed by electrodeposition of Pt nanoparticles on H-CaFe-Cl-layered double hydroxide modified glassy carbon. Electrochemical impedance spectroscopy and cyclic voltammetry were used to investigate the formation of H-CaFe-Cl-layered double hydroxide film and Pt nanoparticles on the electrode surface. The properties of modified electrode were characterized by field emission scanning electron microscopy and energy dispersive X-ray spectroscopy. The fabricated sensor exhibits outstanding electrocatalytic activities toward the oxidation of phenazopyridine. The oxidation peak current was proportional to the concentration of phenazopyridine from 5 Ã 10â 8 to 6.9 Ã 10â 4 mol Lâ 1 including two linear segments with a detection limit of 6.3 Ã 10â 9 mol Lâ 1 at signal to noise ratio of 3. The proposed method was examined as a selective, simple and precise method for voltammetric determination of phenazopyridine in real samples with satisfactory results.
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Physical and Theoretical Chemistry
Authors
F. Hasanpour, M. Taei, M. Movahedi, A. Pazir,