Article ID Journal Published Year Pages File Type
5410284 Journal of Molecular Liquids 2016 5 Pages PDF
Abstract
In this work, a theoretical model is developed, to investigate in more detail the electric field-temperature phase diagram (E-T) of antiferroelectric liquid crystals. The analysis shows that it is possible to obtain a complete description of the induced electric field transition of this material to deduce the entropies, nature of transition, enthalpies versus transition temperatures and transition electric field. Therefore, a quantitative and qualitative analysis of (E-T) phase diagram for some compounds is given. In addition, the constant current technique shows a significant increase of the cell voltage above the threshold near the electric induced (SmC*A-ferrielectric) transition. This behavior, which appears to be rather similar to the supercooled liquids near glass transition, is also discussed in the present work.
Related Topics
Physical Sciences and Engineering Chemistry Physical and Theoretical Chemistry
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