Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5412063 | Journal of Molecular Liquids | 2013 | 8 Pages |
Abstract
⺠Large-scale simulations reveal the microscopic nature of microheterogeneity in dilute solutions. ⺠Solute association is entropy driven. ⺠Demixing occurs above a lower critical solution temperature (LCST). ⺠Below the LCST aggregate size increases with increasing temperature in accord with experiment.
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Physical and Theoretical Chemistry
Authors
Rini Gupta, G.N. Patey,