| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5412436 | Journal of Molecular Liquids | 2012 | 9 Pages |
Abstract
⺠Conductance of Mg2 +, Ca2 +, Sr2 +, Ba2 + and Ni2 + perchlorates in acetonitrile. ⺠The primary association constant and limiting equivalent conductivities are derived. ⺠Strong solvation of Mg2 + and Ni2 + prevents formation of contact ion pairs. ⺠SrClO4+ and BaClO4+ exist in acetonitrile mainly as contact ion pairs. ⺠The modified theory of dielectric friction describes dynamics of solvated ion.
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Physical Sciences and Engineering
Chemistry
Physical and Theoretical Chemistry
Authors
Oleg N. Kalugin, Vira N. Agieienko, Natalya A. Otroshko,