Article ID Journal Published Year Pages File Type
5412644 Journal of Molecular Liquids 2011 11 Pages PDF
Abstract
► The behavior of the entropy diameter Sd is analyzed for wide class of molecular liquids. ► We show that this characteristic is sensitive to the change of the free volume. ► The model equation of state is proposed to describe adequately the behavior of Sd. ► The fluctuational shift of the entropy diameter is demonstrated.
Keywords
Related Topics
Physical Sciences and Engineering Chemistry Physical and Theoretical Chemistry
Preview
Peculiarities in the behavior of the entropy diameter for molecular liquids as the reflection of molecular rotations and the excluded volume effects
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