Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5412740 | Journal of Molecular Liquids | 2011 | 8 Pages |
Abstract
⺠Limiting partial molar volume of H2O or D2O in propylene carbonate (PC) at T >293.15 K is higher than the molar volume of water isotopologue. ⺠Water â PC affinity prevails over the affinity of solvent molecules to each other, especially, in the solution of D2O in PC. ⺠WaterâPC affinity prevails over the affinity of solvent molecules to each other. This tendency becomes more pronounced in the solution of heavy water in PC. ⺠Excess molar volumes of (water + PC) undergo the negative-to-positive sign inversion with increasing temperature.
Related Topics
Physical Sciences and Engineering
Chemistry
Physical and Theoretical Chemistry
Authors
Evgeniy V. Ivanov, Elena Yu. Lebedeva,