Ultrasonic and viscometric studies of molecular interactions in binary mixtures of formamide with ethanol, 1-propanol, 1,2-ethanediol and 1,2-propanediol at different temperatures

The ultrasonic speeds, u and viscosities, η of binary mixtures of formamide (FA) with ethanol, 1-propanol, 1,2-ethanediol, and 1,2-propanediol, including those of pure liquids, over the entire composition range were measured at 293.15, 298.15, 303.15, 308.15, 313.15, and 318.15 K. From the experimental values of u and η, the deviations in isentropic compressibility, Δks, in ultrasonic speed, Δu, and in viscosity, Δη were calculated. The variation of these parameters with composition and temperature of the mixtures are discussed in terms of molecular interaction in these mixtures. The observed trends in Δks values indicate the presence of specific interactions between FA and alkanol molecules. The Δks values follow the order: ethanol < 1-propanol < 1,2-propanediol < 1,2-ethanediol. It is observed that the Δks values depend upon the number of hydroxyl groups and alkyl chain length in these alkanol molecules. Furthermore, the free energies, ΔG⁎, enthalpies, ΔH⁎ and entropies, ΔS⁎ of activation of viscous flow have also been obtained by using Eyring viscosity equation and their dependence on composition of the mixtures have been discussed.