Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5413824 | Journal of Molecular Liquids | 2006 | 12 Pages |
Abstract
The Kirkwood-Buff integrals and the volume-corrected preferential solvation parameters for the first solvation shell are reported for binary mixtures of 1,4-dioxane with many organic solvents. They are calculated from reported thermodynamic data at the temperatures for which these data are available. The co-solvents include n-hexane, n-heptane, c-hexane, methyl-c-hexane, benzene, toluene, ethylbenzene, methanol, ethanol, 1-propanol, 2-propanol, c-pentanol, 1,2-ethanediol, acetic acid, dichloromethane, chloroform, tetrachloromethane, 1,2-dichloroethane, 1,2-dibromoethane, trichloroethene, tetrachloroethene, bromochlorotrifluoroethane (halothane), hexafluorobenzene, acetonitrile, triethylamine, piperidine, formamide, N,N-dimethylformamide, dimethyl sulfoxide, and tetramethylene sulfone (sulfolane). The derived preferential solvation parameters of these mixtures are discussed in terms of the interactions that take place.
Related Topics
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Authors
Yizhak Marcus,