Article ID Journal Published Year Pages File Type
5414777 Journal of Molecular Spectroscopy 2013 4 Pages PDF
Abstract
► Developed a semiempirical expression for the vibrational index at dissociation. ► Expression applies to ground states of neutral diatomic molecules having integral non-zero bond-orders. ► Expression applies to diatomic molecules having Birge-Sponer plots with negative curvature near dissociation. ► Expression does not apply to diatomic molecules that display inconsistency with Badger's rule. ► Employed the expression to make predictions for many molecules that have not been studied near the dissociation limit.
Related Topics
Physical Sciences and Engineering Chemistry Physical and Theoretical Chemistry
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