Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5414777 | Journal of Molecular Spectroscopy | 2013 | 4 Pages |
Abstract
⺠Developed a semiempirical expression for the vibrational index at dissociation. ⺠Expression applies to ground states of neutral diatomic molecules having integral non-zero bond-orders. ⺠Expression applies to diatomic molecules having Birge-Sponer plots with negative curvature near dissociation. ⺠Expression does not apply to diatomic molecules that display inconsistency with Badger's rule. ⺠Employed the expression to make predictions for many molecules that have not been studied near the dissociation limit.
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Physical Sciences and Engineering
Chemistry
Physical and Theoretical Chemistry
Authors
Photos G. Hajigeorgiou,