Nuclear hyperfine structure in the donor-acceptor complexes (CH3)3N-BF3 and (CH3)3N-B(CH3)3

Article ID	Journal	Published Year	Pages	File Type
5414809	Journal of Molecular Spectroscopy	2012	4 Pages	PDF

Abstract

âº Rotational spectra of (CH3)3NâBF3 and (CH3)3NâB(CH3)3 have been observed in a jet. âº Quadrupole coupling constants for 10B, 11B, and 14N have been obtained. âº In both complexes, (CH3)3N donates â¼0.4 electrons to the donor-acceptor bond.

Keywords

electron transfer hyperfine structure Donor–acceptor complex

Related Topics

Physical Sciences and Engineering Chemistry Physical and Theoretical Chemistry

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Nuclear hyperfine structure in the donor-acceptor complexes (CH3)3N-BF3 and (CH3)3N-B(CH3)3

Authors

Sherri W. Hunt, Denise L. Shelley, Kenneth R. Leopold,