High-resolution infrared studies of the Î½10, Î½11, Î½14, and Î½18 levels of [1.1.1]propellane

Article ID	Journal	Published Year	Pages	File Type
5414816	Journal of Molecular Spectroscopy	2012	12 Pages	PDF

Abstract

âº High resolution infrared spectra of propellane (C5H6). âº A rovibrational analysis that accounts for effects of strong Coriolis interactions. âº Comparisons with results from quantum calculations at the anharmonic level. âº A determination of the C0 rotational constant from spectral perturbations. âº A value of 1.586Â Çº for the length of the novel axial CC bond in propellane.

Keywords

Coriolis interactions Rovibrational constants Ground state structure High-resolution infrared spectrum Anharmonic frequencies DFT calculations Propellane

Related Topics

Physical Sciences and Engineering Chemistry Physical and Theoretical Chemistry

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High-resolution infrared studies of the Î½10, Î½11, Î½14, and Î½18 levels of [1.1.1]propellane

Authors

Robynne Kirkpatrick, Tony Masiello, Matthew Martin, Joseph W. Nibler, Arthur Maki, Alfons Weber, Thomas A. Blake,