| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5415120 | Journal of Molecular Spectroscopy | 2011 | 12 Pages |
Abstract
⺠Metal carbonyl cations are produced in a molecular beam by laser vaporization. ⺠Ions are mass-selected and studied with IR photodissociation spectroscopy. ⺠C-O stretching frequencies are measured for M(CO)n+ cations for n = 1-9. ⺠C-O frequencies for cations are compared to those for neutrals. ⺠Stable coordination numbers vary from two to eight for different metals.
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Authors
A.M. Ricks, Z.E. Reed, M.A. Duncan,