Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5415145 | Journal of Molecular Spectroscopy | 2010 | 4 Pages |
Abstract
Natural germanium and selenium consist of, respectively, five and six stable isotopes. Several of these isotopes have considerable abundances and one should expect to observe the bands of at least six isotopic variants of germanium monoselenide (GeSe). In this paper, for the first time, the results of the high-resolution electronic spectrum of the main transition A1Î -X1Σ+ of the specific isotopomer 74Ge80Se, excited in a microwave discharge and recorded in the 33 500-26 000 cmâ1 region using a Fourier transform spectrometer, is discussed. From the rotational analysis of 25 bands involving vâ³Â = 0-12 and vâ²Â = 0-7, accurate vibrational and rotational constants of the A1Î state are determined. The present study has revealed perturbations in the vâ²Â = 6 and 7 levels of the A1Î state.
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Authors
B.J. Shetty, Adya P. Mishra, R.J. Kshirsagar, Richard D'Souza,