| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5415179 | Journal of Molecular Spectroscopy | 2011 | 6 Pages |
Abstract
⺠Microwave measurements on CHT-Ti-CP reveal changes in the structure of the ligands. ⺠DFT and ab-initio calculations can predict accurate structures for organometallic complexes. ⺠Our data shows that the cycloheptatriene protons “droop” towards the metal by a 8.0° angle. ⺠Microwave measurements and theory are in agreement form cycloheptatriene-Cr-cyclopentadiene. ⺠Comparisons with other metals, Zr, Hf, Mo and W show similar structures.
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Physical Sciences and Engineering
Chemistry
Physical and Theoretical Chemistry
Authors
Adam M. Daly, Catherine M. Lavin, Erika S. Weidenschilling, Alison M. Holden, Stephen G. Kukolich,