Article ID Journal Published Year Pages File Type
5415198 Journal of Molecular Spectroscopy 2011 5 Pages PDF
Abstract
► We investigate the emission spectrum of the A2Π-X2Σ+ transition of the AlH+ molecule. ► The full rotational structure of the 0-0 and 1-1 bands is observe and analyze. ► The breaking-off in the intensity of rotational lines of the 0-0 band at J″ = 36.5 is due to the dissociation phenomena in the X2Σ+ state of AlH+. ► Molecular constants is determine for the X2Σ+ state. ► An anomalous Λ-doubling of the A2Π state is the result of an interaction with unstableness rotational levels of X2Σ+ state and perturbing of the A2Π state by the nearly lying B2Σ+ state.
Related Topics
Physical Sciences and Engineering Chemistry Physical and Theoretical Chemistry
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