Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5415198 | Journal of Molecular Spectroscopy | 2011 | 5 Pages |
Abstract
⺠We investigate the emission spectrum of the A2Î -X2Σ+ transition of the AlH+ molecule. ⺠The full rotational structure of the 0-0 and 1-1 bands is observe and analyze. ⺠The breaking-off in the intensity of rotational lines of the 0-0 band at Jâ³Â = 36.5 is due to the dissociation phenomena in the X2Σ+ state of AlH+. ⺠Molecular constants is determine for the X2Σ+ state. ⺠An anomalous Î-doubling of the A2Î state is the result of an interaction with unstableness rotational levels of X2Σ+ state and perturbing of the A2Î state by the nearly lying B2Σ+ state.
Related Topics
Physical Sciences and Engineering
Chemistry
Physical and Theoretical Chemistry
Authors
Wojciech Szajna, MirosÅaw Zachwieja,