Article ID Journal Published Year Pages File Type
5415217 Journal of Molecular Spectroscopy 2010 6 Pages PDF
Abstract
Rotational spectra for the normal isotopic species and all possible 13C single substitutions were observed for the gauche-gauche and anti-gauche conformers, allowing a Kraitchman substitution structure and an inertial fit structure to be determined. 13C isotopic species and dipole moment components were not measurable for the less intense anti-anti species as a result of partially resolved fine splitting. Details of the new chirped-pulse instrument will be described and the structural results will be presented and compared with ab initio data for 3,3-difluoropentane.
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Physical Sciences and Engineering Chemistry Physical and Theoretical Chemistry
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