Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5415217 | Journal of Molecular Spectroscopy | 2010 | 6 Pages |
Abstract
Rotational spectra for the normal isotopic species and all possible 13C single substitutions were observed for the gauche-gauche and anti-gauche conformers, allowing a Kraitchman substitution structure and an inertial fit structure to be determined. 13C isotopic species and dipole moment components were not measurable for the less intense anti-anti species as a result of partially resolved fine splitting. Details of the new chirped-pulse instrument will be described and the structural results will be presented and compared with ab initio data for 3,3-difluoropentane.
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Chemistry
Physical and Theoretical Chemistry
Authors
Daniel A. Obenchain, Ashley A. Elliott, Amanda L. Steber, Rebecca A. Peebles, Sean A. Peebles, Charles J. Wurrey, Gamil A. Guirgis,