| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5415275 | Journal of Molecular Spectroscopy | 2011 | 22 Pages |
Abstract
⺠EF levels of D2 are excited in two steps from the ground state, then fluoresce. ⺠The measured lifetimes disagree strongly with adiabatic ab initio calculations. ⺠The reason - EF levels are strongly mixed with other singlet gerade states. ⺠Accounting for this non-adiabatic mixing improves agreement with experiment. ⺠Strong rotational variation of lifetimes results from accidental near-resonance.
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Physical Sciences and Engineering
Chemistry
Physical and Theoretical Chemistry
Authors
Stephen C. Ross, Koichi Tsukiyama,