Article ID Journal Published Year Pages File Type
5415385 Journal of Molecular Spectroscopy 2009 7 Pages PDF
Abstract
Helium broadening coefficients for the R(10) and the P(2) lines in the ν3 band of 13CO2 have been measured over a large range of temperature (70 K-300 K). Helium pressure shifts for the R(10) line at several temperatures between 100 K and 300 K have also been determined. These measurements were obtained with a cold Herriott cell, using the collisional cooling technique to reach the lowest temperatures. They provide an extended dataset for the temperature dependence of widths and shifts. This dataset was compared to theoretical He-broadening coefficients combining quantum scattering calculations and the latest potential energy surface for the system He-CO2 from Korona et al. [T. Korona, R. Moszynski, F. Thibault, J.-M. Maunay, B. Bussery-Honvault, J. Boissoles, P.E.S. Wormer, J. Chem. Phys. 115 (2001) 3074-3084].
Related Topics
Physical Sciences and Engineering Chemistry Physical and Theoretical Chemistry
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