Article ID Journal Published Year Pages File Type
5415502 Journal of Molecular Spectroscopy 2008 4 Pages PDF
Abstract
Hönl-London factors are the factors that give the dependence of spectroscopic line intensities on the rotational quantum numbers. Recently it has been shown that most tabulations of Hönl-London factors for singlet-singlet transitions do not allow for the special cases of Π-Σ and Σ-Π transitions, where a consideration of the parity symmetrisation shows that an extra factor of 2 is required. The present paper extends these considerations to multiplet transitions, in either pure Hund's case a or pure Hund's case b.
Related Topics
Physical Sciences and Engineering Chemistry Physical and Theoretical Chemistry
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