Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5415671 | Journal of Molecular Spectroscopy | 2009 | 7 Pages |
Abstract
A global fit within experimental accuracy of microwave rotational transitions in the ground and first excited torsional states (vt = 0 and 1) of methylformate (HCOOCH3) is reported, which combines older measurements from the literature with new measurements from Kharkov. In this study the so-called ''rho axis method'' that treats simultaneously both A and E species of the ground and first excited torsional states is used. The final fit requires 55 parameters to achieve an overall unitless weighted standard deviation of 0.71 for a total of 10533 transitions (corresponding to 9298 measured lines) with rotational quantum numbers up to J ⩽ 62 and Ka ⩽ 26 in the ground state and J ⩽ 35 and Ka ⩽ 23 in the first excited torsional state. These results represent a significant improvement over past fitting attempts, providing for the first time a fit within experimental accuracy of both ground and first excited torsional states.
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Physical and Theoretical Chemistry
Authors
V. Ilyushin, A. Kryvda, E. Alekseev,