Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5415698 | Journal of Molecular Spectroscopy | 2008 | 6 Pages |
Abstract
Two-colour polarisation labelling experiments measuring the D-X system of NaK have furnished observations of the D 1Î state of NaK up to vâ³Â = 42. The last observed level is located 7 cmâ1 below the Na(3p 2P3/2) + K(4s) atomic asymptote, 22247.15 cmâ1 above the minimum of the electronic ground state, clearly indicating the dissociation products of this state. The vibrational progressions all exhibit irregular intervals, predominantly because of strong interactions with the nearby d 3Î state, which also dissociates to Na(3p) + K(4s) atoms. The polarisation data have been combined with some resolved fluorescence D-X transitions, and analysed by fitting to spectroscopic parameters and to an analytical potential curve. A full deperturbation treatment has not been attempted, but a 'robust' weighting scheme has been used to reduce the influence of levels that cannot be properly represented by a single channel model. Parameters determined in a fit to a potential curve include Te = 20090.18 ± 0.02 cmâ1, well depth 2157.0 ± 0.3 cmâ1, Re = 4.1547 ± 0.0002 Ã
, with an unweighted root mean square error of 0.12Â cmâ1 for 959 data.
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Physical and Theoretical Chemistry
Authors
A. Adohi-Krou, W. Jastrzebski, P. Kowalczyk, A.V. Stolyarov, A.J. Ross,