Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5415846 | Journal of Molecular Spectroscopy | 2007 | 5 Pages |
Abstract
The microwave rotational spectra of the trans conformer of 3-fluorophenol have been observed in excited torsional states and analyzed in the frequency range 12.0-43.0Â GHz using conventional microwave and Radio-Frequency Microwave Double Resonance (RFMWDR) techniques. Analysis of the ground torsional state spectrum has been extended to higher rotational states. Least-squares analysis of three sets of rotational transitions yield rotational and centrifugal distortion constants for the ground and first two excited torsional states. A nonlinear behavior of the variation of inertial defect with the torsional quantum number was observed.
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Physical and Theoretical Chemistry
Authors
A.I. Jaman,