Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5415986 | Journal of Molecular Spectroscopy | 2007 | 4 Pages |
Abstract
The electric dipole moment of bromofluoromethane, CH279BrF, has been determined with a good accuracy by observing the second order ÎMJ = 0 Stark spectrum of the J = 32,1 â 31,2, J = 52,3 â 51,4 and J = 52,4 â 51,5 rotational transitions. In addition, the equilibrium geometry and dipole moment have been evaluated using highly accurate ab initio calculations. By comparing the experimental [μa = 0.3466(11) D and μb = 1.704(26) D] and theoretical [μa = â0.339 D and μb = â1.701 D] dipole moment components, a very good agreement has been found.
Related Topics
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Physical and Theoretical Chemistry
Authors
Gabriele Cazzoli, Cristina Puzzarini, Agostino Baldacci, Alessandro Baldan,