Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5416102 | Journal of Molecular Spectroscopy | 2006 | 11 Pages |
Abstract
Spectra of the B3Σâ- X3Σâ transition in SO above the first dissociation limit are recorded using degenerate four wave mixing. These spectra are combined with earlier work involving laser induced fluorescence, absorption spectra and Fourier transform emission spectra, to enable a rotational analysis and deperturbation of vibrational levels of the B state up to vâ²Â = 16. Numerous perturbations were noted within the B3Σâ state, and the origin of these is discussed. In a number of cases, these perturbations can be attributed to interactions with specific other electronic states of SO, such as A3Î , C3Î , d1Î , and Aâ³ 3Σ+.
Related Topics
Physical Sciences and Engineering
Chemistry
Physical and Theoretical Chemistry
Authors
Ching-Ping Liu, Nicola L. Elliott, Colin M. Western, Yuan-Pern Lee, Reginald Colin,