Article ID Journal Published Year Pages File Type
5416630 Journal of Molecular Structure: THEOCHEM 2010 5 Pages PDF
Abstract
Origin of rhomboid structures in B4 units were clarified for cationic, neutral, and anionic states. The molecular distortions are due to vibronic interactions of non-degenerate ground states, of which symmetries are lowered from D4h to D2h point group. Multicentered bondings with σ characters were naturally deduced from the vibronic interactions.
Related Topics
Physical Sciences and Engineering Chemistry Physical and Theoretical Chemistry
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