Article ID Journal Published Year Pages File Type
5417015 Journal of Molecular Structure: THEOCHEM 2010 6 Pages PDF
Abstract
We show that our procedure of constructing excited-state energy functionals by splitting k-space, employed so far to obtain exchange energies of excited-states, is quite general. We do so by applying the same method to construct modified Thomas-Fermi kinetic energy functional and its gradient-expansion up to the second order for the excited-states. We show that the resulting kinetic energy functional has the same accuracy for the excited-states as the ground-state functionals do for the ground-states.
Related Topics
Physical Sciences and Engineering Chemistry Physical and Theoretical Chemistry
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