Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5420271 | Solid State Nuclear Magnetic Resonance | 2015 | 7 Pages |
The garnet-type solid conductor Li7âxLa3Zr2âxTaxO12 is known to have high ionic conductivity. We synthesized a series of compositions of this conductor and found that cubic Li6.6La3Zr1.6Ta0.4O12 (LLZO-Ta) has a high ionic conductivity of 3.7Ã10â4 Scmâ1 at room temperature. The 7Li NMR spectrum of LLZO-Ta was composed of narrow and broad components, and the linewidth of the narrow component varied from 0.69 kHz (300 K) to 0.32 kHz (400 K). We carried out lithium ion diffusion measurements using pulsed-field spin-echo (PGSE) NMR spectroscopy and found that echo signals were observed at Tâ¥313 K with reasonable sensitivity. The lithium diffusion behavior was measured by varying the observation time and pulsed-field gradient (PFG) strength between 313 and 384 K. We found that lithium diffusion depended significantly on the observation time and strength of the PFG, which is quite different from lithium ion diffusion in liquids. It was shown that lithium ion migration in the solid conductor was distributed widely in both time and space.
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