Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5420420 | Solid State Nuclear Magnetic Resonance | 2013 | 7 Pages |
â¢Advanced 2-D NMR experimentation on gold (I) diphosphacyclobutadiene complexes.â¢Relativistic chemical shift calculations of gold (I) diphosphacyclobutadiene complexes.â¢Correction of a spectral assignment in the literature.
The 31P and 13C solid state nuclear magnetic resonance spectra of a neutral gold(I) complex with bis(diphosphacyclobutadiene) cobaltate anions, [Au{Co(P2C2tPent2)2}2(PMe3)2], are reported. Complete 31P resonance assignments have been derived from saturation transfer, radio-frequency driven recoupling (RFDR) and RTOBSY experiments and confirmed further by ab-initio calculations of magnetic shielding tensors by density functional theory, with consideration of relativistic effects. Coordination of the diphosphacyclobutadiene ring with gold(I) results in a high-frequency shift of the 31P signal of the directly coordinated P atom, whereas a low-frequency shift is observed for the P atom at the opposite end of that ring. Based on these results, a previous assignment made for the complex salts [Au(PMe3)4][Au{Co(P2C2Ad2)2}2] and [K(18-crown-6)(thf)2][Au{Co(P2C2Ad2)2}2] (Ad=adamantyl) must be corrected.
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