Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5420720 | Solid State Nuclear Magnetic Resonance | 2008 | 4 Pages |
Abstract
Various inorganic selenium-based compounds were analysed by 77Se solid-state NMR, and a distinct difference in chemical shift ranges for compounds where selenium is present as selenide (Se2â) ionically and covalently bonded systems was observed. The selenides exhibit a shift range of approximately â700 to â100Â ppm, as opposed to 700 to 1600Â ppm for the compounds where there tends to be more direct covalent bonding to the selenium. The anisotropic hyperfine shift observed in NbSe2 is shown to be axially symmetric, where the H11 component is found to be normal to the Se3-trigonal plane.
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Physical Sciences and Engineering
Chemistry
Physical and Theoretical Chemistry
Authors
T.F. Kemp, A. Wong, M.E. Smith, P.T. Bishop, N. Carthey,