Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5420829 | Solid State Nuclear Magnetic Resonance | 2009 | 7 Pages |
Abstract
Ethane conversion into aromatic hydrocarbons over Zn-modified zeolite BEA has been analyzed by high-temperature MAS NMR spectroscopy. Information about intermediates (Zn-ethyl species) and reaction products (mainly toluene and methane), which were formed under the conditions of a batch reactor, was obtained by 13C MAS NMR. Kinetics of the reaction, which was monitored by 1H MAS NMR in situ at the temperature of 573Â K, provided information about the reaction mechanism. Simulation of the experimental kinetics within the frames of the possible kinetic schemes of the reaction demonstrates that a large amount of methane evolved under ethane aromatization arises from the stage of direct ethane hydrogenolysis.
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Authors
Sergei S. Arzumanov, Anton A. Gabrienko, Dieter Freude, Alexander G. Stepanov,