Article ID Journal Published Year Pages File Type
5421828 Surface Science 2015 4 Pages PDF
Abstract

- “Simple thermodynamic derivation of the electrocapillary equations” contains mathematical errors.
- We propose a simplest derivation of the electrocapillary equation using the Gibbs-Duhem relation.
- The both Gokhstein's equations are only artificially distorted forms of the Lippmann equation.
- Therefore, attempts to evaluate validity of the Gokhstein equations are senseless.
- The Lippmann equation does not require checks of its validity as it has been shown earlier.
Related Topics
Physical Sciences and Engineering Chemistry Physical and Theoretical Chemistry
Authors
,