Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5422635 | Surface Science | 2013 | 7 Pages |
Abstract
⺠Catalytically active nanoporous gold was studied in UHV by XPS and TPD. ⺠Active and inactive surface oxygen species were identified on the catalyst surface. ⺠Active oxygen consumed by exposure to CO can be replenished by exposure to O2. ⺠CO2 evolution is linked to a CO desorption state at temperatures above 200 K. ⺠Residual silver and inactive oxygen may cause O2 activation and CO stabilization.
Related Topics
Physical Sciences and Engineering
Chemistry
Physical and Theoretical Chemistry
Authors
Sarah Röhe, Kristian Frank, Andreas Schaefer, Arne Wittstock, Volkmar Zielasek, Andreas Rosenauer, Marcus Bäumer,