Article ID Journal Published Year Pages File Type
5422686 Surface Science 2012 7 Pages PDF
Abstract
► Two model Rh/γ-Al2O3 catalysts are designed as Rh/Al8O26H27 and Rh/Al8O26H26. ► Rh/Al8O26H27 is more active toward methane activation than Rh/Al8O26H26. ► Lower substrate activation strain ΔE≠strain[substr] causes lower of activation barriers. ► These results are in qualitative agreement with the experimental results.
Related Topics
Physical Sciences and Engineering Chemistry Physical and Theoretical Chemistry
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