Article ID Journal Published Year Pages File Type
5422932 Surface Science 2011 10 Pages PDF
Abstract
► HT CO-desorption from TiO2 + Rh + COsat corresponds to C+O reaction on the titania support. ► Lack of CO2 suggests that O atoms arising from CO bind to reduced centers of titania. ► Preformed Mo particles increase the dispersion of rhodium deposit. ► Extended CO dissociation on Mo-Rh particles stems mainly from reaction with Mo. ► The Mo2C formed is a possible source of enhanced catalytic activity of Mo-Rh clusters.
Related Topics
Physical Sciences and Engineering Chemistry Physical and Theoretical Chemistry
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